Details
99% Purity Commercial production (-)-ISOCARYOPHYLLENE 118-65-0 with Cheapest Price
- Molecular Formula: C15H24
- Molecular Weight: 204.356
- Vapor Pressure: 0.0128mmHg at 25°C
- Melting Point: 25°C
- Refractive Index: n20/D 1.496
- Boiling Point: 268.4°Cat760mmHg
- Flash Point: 104.9°C
- PSA: 0.00000
- Density: 0.89g/cm3
- LogP: 4.72520
(-)-ISOCARYOPHYLLENE(Cas 118-65-0) Usage
|
Purification Methods |
Purify it by vacuum distillation or GLC using a nitrile-silicone column [Corey et al. J Am Chem Soc 86 485 1964, Ramage & Simonsen J Chem Soc 741 1936, Kumar et al.Synthesis 461 1976]. [Beilstein 5 III 1085.] |
InChI:InChI=1/C15H24/c1-11-6-5-7-12(2)13-10-15(3,4)14(13)9-8-11/h6,13-14H,2,5,7-10H2,1,3-4H3/b11-6-/t13-,14-/m1/s1
118-65-0 Relevant articles
Transformations of isocaryophyllene diepoxide under conditions of homogeneous and heterogeneous acid catalysis
Salomatina,Yarovaya,Korchagina,Gatilov,Polovinka,Barkhash
, p. 1280 - 1285 (2005)
Transformations of isocaryophyllene diep...
Electron transfer-initiated epoxidation and isomerization chain reactions of β-caryophyllene
Steenackers, Bart,Campagnol, Nicol,Fransaer, Jan,Hermans, Ive,De Vos, Dirk
, p. 2146 - 2156 (2015/01/30)
The abundant sesquiterpene b-caryophylle...
Transannular cyclization of epoxycaryophyllenes catalyzed by Ti III: An efficient synthesis of tricyclo[6.3.0.02,5] undecanes
Barrero, Alejandro F.,Herrador, M. Mar,Quilez Del Moral, Jose F.,Arteaga, Pilar,Sanchez, Elena M.,Arteaga, Jesus F.,Piedra, Maria
, p. 3434 - 3441 (2007/10/03)
The transannular cyclization of epoxycar...
Betulenols from Betula species
Demirci, Betuel,Huesnue Can Baser,Oezek, Temel,Demirci, Fatih
, p. 490 - 493 (2007/10/03)
The essential oils from buds of five Bet...
118-65-0 Process route
-
-
87-44-5
β-caryophyllene
-
-
58404-89-0,82008-48-8,129445-45-0,472-97-9
β-caryolanol
-
-
131717-65-2
isocaryolan-8-ol
-
-
118-65-0
(-)-isocaryophyllene
-
-
56684-96-9
β-neoclovene
| Conditions | Yield |
|---|---|
|
With
sulfuric acid;
In
diethyl ether;
at 0 - 20 ℃;
for 0.5h;
Further byproducts given;
|
26.1%
2.5% 10 mg |
|
With
sulfuric acid;
In
diethyl ether;
at 0 - 20 ℃;
for 0.5h;
Yield given. Further byproducts given. Title compound not separated from byproducts;
|
26.1%
2.5% 10 mg |
-
-
87-44-5
β-caryophyllene
-
-
58404-89-0,82008-48-8,129445-45-0,472-97-9
β-caryolanol
-
-
131717-65-2
isocaryolan-8-ol
-
-
118-65-0
(-)-isocaryophyllene
-
-
56633-28-4,77286-73-8
(-)-α-panasinsen
| Conditions | Yield |
|---|---|
|
With
sulfuric acid;
In
diethyl ether;
at 0 - 20 ℃;
for 0.5h;
Yield given. Further byproducts given;
|
26.1%
2.5% 10 mg |
118-65-0 Upstream products
-
87-44-5
β-caryophyllene
-
60594-22-1
caryophyllene oxide
-
60362-45-0
8-Oxo-4,11,11-trimethylbicyclo <7.2.0> undec-4-en 7.2.0>
-
61824-50-8
(Z)-(1R,9S)-4,11,11-Trimethyl-8-methylene-bicyclo[7.2.0]undec-3-en-5-one
118-65-0 Downstream products
-
597-43-3
2,2-dimethylsuccinic acid
-
496-99-1
(+)-trans-Norcaryophyllensaeure
-
1217184-42-3
(1S,2S,5R,8R)-4,4,8-trimethyltricyclo[6.3.1.0(2,5)]dodecanyl acetate
-
57082-24-3
caryophyllene acetate
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